When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | Cl2_IUPAC(2007)_298K_260-470nm(rec).txt |
NAME: | chlorine |
FORMULA: | Cl2 |
AUTHOR(YEAR): | IUPAC(2007) |
T: | 298K |
λ: | 260-470nm(rec) |
BIBLIOGRAPHY: |
R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, and J. Troe, "Evaluated kinetic and photochemical data for atmospheric chemistry: Volume III - gas phase reactions of inorganic halogens",
Atmos. Chem. Phys. 7, 981-1191 (2007);
DOI: 10.5194/acp-7-981-2007
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COMMENTS: | IUPAC recommendation (2007): The preferred values of the absorption cross-sections at 298 K are the values reported by D. Maric, J.P. Burrows, R. Meller, and G.K. Moortgat, "Visible absorption spectra of molecular chlorine," J. Photochem. Photobiol. A: Chem. 70, 205-214 (1993); DOI: 10.1016/1010-6030(93)85045-A , who fitted the data for the wavelength region 250-550 nm with the following semi-empirical expression: 1020 σ = α0.5 × 27.3 exp {-99.0 α × [ln(329.5/λ)]2} + α0.5 × 0.932 exp {-91.5 α × [ln(406.5/λ)]2}
where α = tanh (402.676/T). |
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