The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


Home

Cross Sections

Quantum Yields

Errata

Contact, Imprint, Acknowledgements


When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Halogens+mixed halogens / Cl2 / IUPAC(2007)_298K_260-470nm(rec)

DATAFILE: Cl2_IUPAC(2007)_298K_260-470nm(rec).txt
NAME: chlorine
FORMULA: Cl2
AUTHOR(YEAR): IUPAC(2007)
T: 298K
λ: 260-470nm(rec)
BIBLIOGRAPHY: R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, and J. Troe, "Evaluated kinetic and photochemical data for atmospheric chemistry: Volume III - gas phase reactions of inorganic halogens", Atmos. Chem. Phys. 7, 981-1191 (2007); DOI: 10.5194/acp-7-981-2007
COMMENTS: IUPAC recommendation (2007):

The preferred values of the absorption cross-sections at 298 K are the values reported by

D. Maric, J.P. Burrows, R. Meller, and G.K. Moortgat, "Visible absorption spectra of molecular chlorine," J. Photochem. Photobiol. A: Chem. 70, 205-214 (1993); DOI: 10.1016/1010-6030(93)85045-A ,

who fitted the data for the wavelength region 250-550 nm with the following semi-empirical expression:

1020 σ = α0.5 × 27.3 exp {-99.0 α × [ln(329.5/λ)]2} + α0.5 × 0.932 exp {-91.5 α × [ln(406.5/λ)]2}

where α = tanh (402.676/T).

Search cross sections

Species search:

Identifier search:

Reference search:

Full text search:

Recent additions:
since ago